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Properties of substance:
chromium(III) chloride
Group of substances:
inorganic
Physical appearance:
monoclinic crystals
Empirical formula (Hill's system for organic substances):
Cl
3
Cr
Structural formula as text:
CrCl3
Molar/atomic mass: 158.36
Sublimation point (°C):
950
Solubility (g/100 g of solvent):
acetaldehyde
: insoluble [
Ref.
]
acetone
: sparingly soluble [
Ref.
]
diethyl ether
: sparingly soluble [
Ref.
]
ethanol
: sparingly soluble [
Ref.
]
ethanol abs.
: insoluble [
Ref.
]
ethyl acetate
: insoluble [
Ref.
]
hydrazine
: 13 (20°C) [
Ref.
]
methanol
: insoluble [
Ref.
]
water
: sparingly soluble [
Ref.
]
Numerical data:
Year of discovery: 1818
Density:
3.03 (20°C, g/cm
3
)
Reactions:
[
Ref.1
,
Ref.2
]
4CrCl
3
+ 3O
2
→ 2Cr
2
O
3
+ 6Cl
2
Vapour pressure (Torr):
1 (684°C)
10 (761°C)
100 (852°C)
Standard molar enthalpy (heat) of formation Δ
f
H
0
(298.15 K, kJ/mol):
-570.3 (s)
Standard molar Gibbs energy of formation Δ
f
G
0
(298.15 K, kJ/mol):
-500.7 (s)
Standard molar entropy S
0
(298.15 K, J/(mol·K)):
124.7 (s)
Molar heat capacity at constant pressure C
p
(298.15 K, J/(mol·K)):
91.8 (s)
Neel temperature (K):
16.8
References:
Гринвуд Н., Эрншо А. Химия элементов. - Т.2. - М.: БИНОМ. Лаборатория знаний, 2008. - pp. 352-353 [Russian]
Некрасов Б.В. Основы общей химии. - Т.1. - М.: Химия, 1973. - pp. 378 [Russian]
Рабинович В.А., Хавин З.Я. Краткий химический справочник. - Л.: Химия, 1977. - pp. 111 [Russian]
Справочник по растворимости. - Т.1, Кн.2. - М.-Л.: ИАН СССР, 1962. - pp. 982 [Russian]
Справочник химика. - Т. 2. - Л.-М.: Химия, 1964. - pp. 244-245 [Russian]
Фурман А.А. Неорганические хлориды (химия и технология). - М.: Химия, 1980. - pp. 348-349 [Russian]
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© Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru