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Properties of substance:

acetoneperoxide



skc-file

Synonyms:

triacetone triperoxide

Group of substances:

organic

Physical appearance:

white prismatic crystals

Empirical formula (Hill's system for organic substances):

C9H18O6

Structural formula as text:

((CH3)2COO)3

Molar/atomic mass: 222.236

Melting point (°C):

97

Sublimation point (°C):

70

Solubility (g/100 g of solvent):

1,2-dichloroethane: very soluble [Ref.]
acetic acid: sparingly soluble [Ref.]
acetone: 10.07 (17°C) [Ref.]
amyl alcohol: sparingly soluble [Ref.]
benzene: 22 (17°C) [Ref.]
carbon disulphide: 8.66 (17°C) [Ref.]
carbon tetrachloride: 33 (17°C) [Ref.]
chloroform: 73.8 (17°C) [Ref.]
diethyl ether: 5.8 (17°C) [Ref.]
ethanol: soluble (78°C) [Ref.]
ethanol abs.: 0.15 (17°C) [Ref.]
ethyl acetate: very soluble [Ref.]
glycerol: sparingly soluble [Ref.]
methanol: slightly soluble [Ref.]
petroleum ether: 7.93 (17°C) [Ref.]
pyridine: 16.28 (17°C) [Ref.]
toluene: very soluble [Ref.]
trichloroethylene: 28.6 (17°C) [Ref.]
water: insoluble [Ref.]
xylene: very soluble [Ref.]

Hygroscopic:

no

Numerical data:

Year of discovery: 1895
Heat of Explosion (kJ/kg): 5668
Detonation velocity (m/s): 3750
Detonation velocity (m/s): 5300

Density:

1.3 (20°C, g/cm3)

Standard molar enthalpy (heat) of formation ΔfH0 (298.15 K, kJ/mol):

-90.8 (s)

References:

  1. Chemicke Listy. - 2013. - vol. 107. - pp. 277-282
  2. Encyclopedia of explosives and related items. - Vol. 1. - 1960. - pp. A42-A45
  3. Matyas R., Pachman J. Primary Explosives. - Springer, 2013. - pp. 262-274
  4. Proceedings of the seventh Seminar New trends in research of energetic materials. - held at the University of Pardubice, Pardubice, the Czech Republic, April 20–22, 2004. - pp. 164-173
  5. Багал Л.И. Химия и технология инициирующих взрывчатых веществ. - М., 1975. - pp. 411-415 [Russian]
  6. Хавкинс Э.Дж.Э. Органические перекиси, их получение и реакции. - М.-Л.: Химия, 1964. - pp. 338-339 [Russian]
  7. Хмельницкий Л.И. Справочник по взрывчатым веществам. - Ч. 2. - М., 1962. - pp. 632-635 [Russian]
  8. Энергетические конденсированные системы. - Под ред. Жукова Б.П., 2-е изд. - М.: Янус-К, 2000. - pp. 351 [Russian]

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    © Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru