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Properties of substance:
samarium(II) iodide
Group of substances:
inorganic
Physical appearance:
green monoclinic crystals
Empirical formula (Hill's system for organic substances):
I
2
Sm
Structural formula as text:
SmI2
Molar/atomic mass: 404.17
Melting point (°C):
520
Boiling point (°C):
1660
Solubility (g/100 g of solvent):
acetonitrile
: soluble [
Ref.
]
ethanol
: soluble [
Ref.
]
hexamethylphosphoric triamide
: soluble [
Ref.
]
tetrahydrofuran
: 4.54 (20°C) [
Ref.
]
References:
Journal of Organic Chemistry. - 2014. - Vol. 79, No. 6. - pp. 2522-2537 [DOI:
10.1021/jo4028243
]
Procter D.J., Flowers R.A. II, Skrydscrup T. Organic Synthesis Using Samarium Diiodide. A Practical Guide. - 2010
Гринвуд Н., Эрншо А. Химия элементов. - Т.2. - М.: БИНОМ. Лаборатория знаний, 2008. - pp. 559 [Russian]
Ефимов А.И. и др. Свойства неорганических соединений. Справочник. - Л.: Химия, 1983. - pp. 186-187 [Russian]
Иост Д., Рэссель Г., Гарнер К. Редкоземельные элементы и их соединения. - М.: ИИЛ, 1949. - pp. 97 [Russian]
Успехи химии. - 1994. - Т.63, №4. - pp. 361-372 [Russian]
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© Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru