Main page (Russian) Search in database (English)

Properties of substance:

propenenitrile

Synonyms:

acrylonitrile

Group of substances:

organic

Physical appearance:

colorless liquid

Empirical formula (Hill's system for organic substances):

C3H3N

Structural formula as text:

CH2=CHCN

Molar/atomic mass: 53.06

Melting point (°C):

-82

Boiling point (°C):

79

Solubility (g/100 g of solvent):

acetone: very soluble [Ref.]
benzene: very soluble [Ref.]
diethyl ether: miscible [Ref.]
ethanol: miscible [Ref.]
sulfolane: miscible [Ref.]
water: 6.716 (0°C) [Ref.]
water: 6.803 (20°C) [Ref.]
water: 8.173 (59°C) [Ref.]
water: 11.27 (90°C) [Ref.]

Density:

0.797 (20°C, d4)

Reactions:

  1. Yeild 71%. [Ref.1aster]
    C6H5NH2 + (CH3)3CONO + CH2=CHCN + CuCl2 → C6H5CH2CHClCN + N2 + Cu(OH)Cl + (CH3)3COH

Standard molar enthalpy (heat) of formation ΔfH0 (298.15 K, kJ/mol):

147.1 (l)

Standard molar enthalpy (heat) of formation ΔfH0 (298.15 K, kJ/mol):

180.6 (g)

LD50 (mg/kg):

93-100 (rabbits, oral)
50 (guinea pig, oral)
20 (mice, oral)

References:

  1. CRC Handbook of Chemistry and Physics. - 90ed. - CRC Press, 2010. - pp. 5-23
  2. Gangolli S. The Dictionary of Substances and their Effects. - 2 ed., Vol. 1, A-B. - RSC, 1999. - pp. 74-78
  3. Lewis R.J. Sax's Dangerous Properties of Industrial Materials. - 11ed. - Wiley-interscience, 2004. - pp. 72-73
  4. Milne G.W.A. Gardner's Commercially Important Chemicals. - Wiley-Interscience, 2005. - pp. 12
  5. Yalkowsky S.H., Yan H., Jain P. Handbook of aqueous solubility data. – 2nd ed. - CRC Press, 2010. - pp. 46
  6. Вредные вещества в промышленности: Справочник для химиков, инженеров и врачей. - 7-е изд., Т.2. - Л.: Химия, 1976. - pp. 105-108 [Russian]
  7. Справочник химика. - Т. 2. - Л.-М.: Химия, 1964. - pp. 406-407 [Russian]
  8. Химический энциклопедический словарь. - Под ред. Кнунянц И.Л. - М.: Советская энциклопедия, 1983. - pp. 17 [Russian]

    What information do you need?




    © Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru