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Properties of substance:
4-chlorophenol
Group of substances:
organic
Physical appearance:
needles crystals
Empirical formula (Hill's system for organic substances):
C
6
H
5
ClO
Structural formula as text:
ClC6H4OH
Molar/atomic mass: 128.56
Melting point (°C):
43
Boiling point (°C):
217
Solubility (g/100 g of solvent):
benzene
: 309 (20°C) [
Ref.
]
diethyl ether
: very soluble [
Ref.
]
ethanol
: very soluble [
Ref.
]
water
: 2.71 (20°C) [
Ref.
]
Density:
1.26 (45°C, g/cm
3
)
Reactions:
Yeild 96%. [
Ref.1
]
HOC
6
H
5
Cl + NH
4
Cl + Zn → HOC
6
H
6
+ ZnCl
2
+ NH
3
Dissociation:
pK
a
(1) = 9.38 (25°C, water)
LD
50
(mg/kg):
1030 (rats, subcutaneous)
1000 (rats, onto the skin)
281 (rats, intraperitoneal)
References:
CRC Handbook of Chemistry and Physics. - 95ed. - CRC Press, 2014. - pp. 3-116
Seidell A. Solubilities of organic compounds. - 3ed., vol.2. - New York: D. Van Nostrand Company, 1941. - pp. 355-356
Yalkowsky S.H., Yan H. Handbook of aqueous solubility data. - CRC Press, 2003. - pp. 223
Альберт А., Сержент Е. Константы ионизации кислот и оснований. - М.-Л.: Химия, 1964. - pp. 126 [Russian]
Вредные химические вещества: Галоген- и кислородсодержащие органические соединения. Справочник. - СПб.: Химия, 1994. - pp. 242-245 [Russian]
Полюдек-Фабини Р., Бейрих Т. Органический анализ. - Л.: Химия, 1981. - pp. 83 [Russian]
Справочник по растворимости. - Т.1, Кн.1. - М.-Л.: ИАН СССР, 1961. - pp. 429 [Russian]
Справочник химика. - Т. 2. - Л.-М.: Химия, 1964. - pp. 1052-1053 [Russian]
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© Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru