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Properties of substance:

chlorine perchlorate

Synonyms:

dichlorine hexoxide

Group of substances:

inorganic

Physical appearance:

oily liquid

Empirical formula (Hill's system for organic substances):

Cl2O6

Structural formula as text:

ClO2ClO4

Molar/atomic mass: 166.902

Melting point (°C):

3

Decomposition temperature (°C):

0

Solubility (g/100 g of solvent):

carbon tetrachloride: soluble [Ref.]
perchloric acid anhydrous: soluble [Ref.]
phosphoric acid: soluble [Ref.]
sulfur dioxide: soluble [Ref.]
trichlorofluoromethane: soluble [Ref.]

Numerical data:

Year of discovery: 1925

Density:

1.81 (0°C, g/cm3)

Reactions of synthesis:

  1. [Ref.1aster, Ref.2]
    2ClO2 + 2O3 → Cl2O6 + 2O2

References:

  1. Advances in Inorganic Chemistry and Radiochemistry. - 1963. - Vol. 5. - pp. 62-66
  2. CRC Handbook of Chemistry and Physics. - 95ed. - CRC Press, 2014. - pp. 4-58
  3. Некрасов Б.В. Основы общей химии. - Т.1. - М.: Химия, 1973. - pp. 265-266 [Russian]
  4. Никитин И.В. Химия кислородных соединений галогенов. - М.: Наука, 1986. - pp. 73-77 [Russian]

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    © Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru