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Properties of substance:

ethyl perchlorate

Group of substances:

organic

Physical appearance:

colorless liquid

Empirical formula (Hill's system for organic substances):

C2H5ClO4

Structural formula as text:

CH3CH2OClO3

Molar/atomic mass: 128.51

Boiling point (°C):

89

Solubility (g/100 g of solvent):

ethanol: soluble [Ref.]
water: insoluble [Ref.]

Numerical data:

Year of discovery: 1841

Reactions of synthesis:

  1. Yeild 47%. [Ref.1]
    C2H5OC(O)Cl + AgClO4 → C2H5OClO3 + AgCl + CO2
  2. Yeild 56%. [Ref.1, Ref.2aster]
    C2H5OH + Cl2O7 → C2H5OClO3 + HClO4
  3. [Ref.1]
    (C2H5OSO3)2Ba + Ba(ClO4)2 → 2C2H5OClO3 + 2BaSO4
  4. [Ref.1]
    3H2NCOOC2H5 + Cl2O7 → C2H5OClO3 + [H2NC(OH)OC2H5]ClO4 + H2NCONHCOOC2H5

References:

  1. Encyclopedia of explosives and related items. - Vol. 6. - New Jersey, 1974. - pp. E316
  2. Urbanski T. Chemistry and technology of explosives. - vol.2. - Warszawa, 1965. - pp. 447-448
  3. Успехи химии. - 1988. - Т.57, №11. - pp. 1815-1839 [Russian]
  4. Химическая энциклопедия. - Т. 3. - М.: Советская энциклопедия, 1992. - pp. 499 [Russian]
  5. Шумахер И. Перхлораты: свойства, производство и применение. - М.: ГНТИХЛ, 1963. - pp. 85 [Russian]

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    © Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru